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   » » Wiki: Cigarette Filter
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A cigarette filter, also known as a filter tip, is a component of a , along with , capsules and adhesives. Filters were introduced in the early 1950s.

Filters may be made from plastic cellulose acetate fiber, or activated charcoal (either as a cavity filter or embedded into the plastic cellulose acetate fibers). Macroporous phenol-formaldehyde resins and have also been used. The plastic cellulose acetate filter and paper modify the particulate smoke phase by particle retention (), and finely divided carbon modifies the gaseous phase ().

Filters are intended to reduce the harm caused by smoking by reducing harmful chemicals inhaled by smokers. While laboratory tests show a reduction of "tar" and in cigarette smoke, filters are ineffective at removing gases of low molecular weight, such as . Most of these measured reductions occur only when the cigarette is smoked on a smoking machine; when smoked by a human, the compounds are delivered into the lungs regardless of whether a filter is used.

Most factory-made cigarettes are equipped with a filter; those who roll their own can buy them from a tobacconist.


History
In 1925, Hungarian inventor Boris Aivaz patented the process of making a cigarette filter from .

From 1935, Molins Machine Co Ltd a British company began to develop a machine that made cigarettes incorporating the tipped filter. It was considered a specialty item until 1954, when manufacturers introduced the machine more broadly, following a spate of announcements from and researchers concerning a possible link between and smoking. Since filtered cigarettes were considered safer, by the 1960s, they dominated the market. Production of filter cigarettes rose from 0.5 percent in 1950 to 87.7 percent by 1975.

Between the 1930s and the 1950s, most cigarettes were long. The modern cigarette market includes mainly filter cigarettes that are .

Cigarettes filters were originally made of cork and used to prevent tobacco flakes from getting on the smoker's tongue. Many are still patterned to look like cork.


Manufacture
Cigarette filters are usually made from plastic cellulose acetate , but sometimes also from or activated charcoal (either as a cavity filter or embedded into the cellulose acetate).

Cellulose acetate is made by or with . Of the three cellulose hydroxy groups available for esterification, between two and three are esterified by controlling the amount of acid (degree of substitution (DS) 2.35-2.55). The ester is spun into fibers and formed into bundles called . Flavors (), , (), (), breakable capsules releasing flavors on demand, and additives colouring the tobacco smoke may be added to cigarette filters. The five largest manufactures of filter tow are and Eastman Chemicals in the United States, Cerdia in Germany, and Mitsubishi Rayon in Japan.

or emulsion-based adhesives are used for gluing cigarette seams. Hot-melt and emulsion-based adhesives are used for filter seams. Emulsion-based adhesives are used for bonding the filters to the cigarettes. The tip paper may be coated with polyvinyl alcohol.


Colour change
The tobacco industry determined that the illusion of filtration was more important than filtration itself. The pH of the cellulose acetate used is modified, so that its colour becomes darker when exposed to smoke (this was invented in 1953 by Claude Teague, working for R. J. Reynolds Tobacco Company).
(2025). 9780520270169, University of California Press.
The industry wanted filters to be seen as effective for marketing reasons, despite not making cigarettes any less unhealthy. Teague said that:


Health risks
In the 1970s epidemiologic evidence relative to tobacco-related cancers and data for coronary heart disease indicated a reduced risk among filter smokers for these diseases. Between 1970 and 1980 some studies showed a 20-50% reduction in risk of lung cancer for long-term smokers of filtered cigarettes as compared to smokers of non-filtered cigarettes (IARC, 1986) but later studies indicated a similar risk for lung cancer in smokers of filtered and non-filtered cigarettes. The risk reductions depend on different aspects such as the gender or whether a person is athletic, the study location, the age of the person, and when only studies providing both unadjusted and adjusted estimates were considered.


Light cigarettes
In spite of the changes in cigarette design and manufacturing over the last fifty years, the use of filters and "light" cigarettes neither decreased the nicotine intake per cigarette, nor lowered the incidence of lung cancer (NCI, 2001; IARC 83, 2004; U.S. Surgeon General, 2004). of cellulose diacetate with one of the acetate groups on the cellulose backbone shown by the red circle]]


Waste
Cigarette butts are the most anthropogenic (man-made) in the world. Approximately 5.6 trillion cigarettes are smoked every year worldwide. Of these, it is estimated that 4.5 trillion cigarette butts become litter every year. The plastic cellulose acetate in cigarette butts biodegrades gradually, passing through the stage of . The breakdown of discarded cigarette butts is highly dependent upon environmental conditions. A 2021 review article cites an experiment where 45-50% of cellulose acetate mass was fully degraded to CO2 after 55 days of controlled composting and another where negligible degradation took place after 12 weeks in pilot-scale compost.

During the act of smoking, plastic cellulose acetate fibers and tipping paper absorb a wide range of chemicals that are present in tobacco smoke. After cigarette butts are discarded, they can leach toxins including nicotine, arsenic, polycyclic aromatic hydrocarbons and heavy metals into the environment. Smoked cigarette butts and cigarette tobacco in butts have been shown to be toxic to water organisms such as the marine topsmelt ( Atherinops affinis) and the freshwater fathead minnow ( Pimephales promelas). Moreover, cigarette filters enriched in toxic substances that enter environmental waterbodies have been shown to be increasingly colonized by potentially pathogenic bacteria including those displaying antibiotic resistance, as these are particularly well adapted to the adverse conditions on the filters. Many governments have sanctioned stiff penalties for littering of cigarette filters; for example Washington State imposes a penalty of $1,025 for littering cigarette filters. Another option is developing better filters. Much of this work relies heavily on the research about the secondary mechanism for photodegradation. However, making a product biodegradable means making it vulnerable to humidity and heat, which does not suit filters made for hot and humid smoke. The next option is using cigarette packs with a compartment for discarded cigarette butts, implementing monetary deposits on filters, increasing the availability of cigarette receptacles, and expanding public education. Others have suggested banning the sale of filtered cigarettes altogether on the basis of their adverse environmental impact.

Recent research has been put into finding ways to use the filter waste in order to develop other products. One research group in South Korea have developed a one-step process that converts the cellulose acetate in discarded cigarette filters into a high-performing supercapacitor electrode material. These materials have demonstrated superior performance as compared to commercially available carbon, and carbon nano tubes.

Another group of researchers has proposed adding tablets of food grade acid inside the filters. Once wet enough the tablets would release acid that accelerates degradation to around two weeks, instead of using cellulose triacetate and besides of cigarette smoke being quite acidic.


Activated charcoal filtration
Cigarette filter can incorporate an activated charcoal filtration system. Instead of acetate or cardboard filters, it consists of two ceramic caps on either sides containing activated charcoal, which reduces tar and other toxins in the smoke.


See also

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